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Plastic materials laser marking

Laser Marking on Plastic

Laser marking stands out as a reliable method for marking and coding various types of plastics.

The technique involves a focused laser beam that creates permanent marks. These durable laser marks remain legible throughout the product's lifecycle. 

Laser marking eliminates the need for consumables, like ink and labels, as well as the waste associated with their use. It is not only economical, but also environmentally friendly.

This method can also help maintain the integrity and safety of the product, as it requires no contact with the plastic surface, eliminating the risk of contamination. This is a significant advantage in industries that are required to meet regulatory standards.

Additionally, laser systems require virtually no preventive maintenance and can be seamlessly integrated into high-speed production lines.

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The Best Type of Laser to Mark Plastic: UV Laser

Different types of lasers can be used to mark plastic, each differing mainly in the way the beam is focused and in the wavelength. Selecting the right system depends on the material and application.

UV Lasers

When it comes to precision and versatility, UV lasers are the best choice to mark plastics. They’re the only lasers with the ability to mark extremely small codes, with standard spot sizes down to  7 um micron. These spot sizes simply cannot be achieved with fiber or CO2 lasers for marking.

One of the main advantages of UV lasers is their ability to interact with several materials through photochemical mechanisms. UV lasers are frequently called “cold lasers,” as the desire is to use them to mark products and not  heat up the surface surrounding or underneath the marked area.

UV lasers can induce color changes on substrates to create high-contrast marks. While fiber lasers can also achieve this effect, they produce heat on the surfaces, and are limited to certain substrates.

Laserax’s DPSS UV lasers offer the largest marking field in the industry at 1 meter, compared to 300 mm for competitors. They also feature a variable focal distance and deliver average power levels of up to 55 W, ensuring effective and high-contrast marking on plastics.

CO2 Lasers

CO2 lasers have been around since the 1960s and are commonly used for general-purpose marking, since they produce deep, high-contrast, and durable marks through thermal processes. Due to their longer wavelengths (typically between 9,300 nm and 10,600 nm), CO2 lasers are more often used to process non-metallic surfaces, such as, wood, paper, glass, cardboard, certain plastics and organic materials. Heat is the main mechanism to change the color of the part by slightly burning, engraving or ablating the material. Spot sizes (resolution) are generally larger than other laser standards, but can work for many applications.

Fiber Lasers 

Fiber lasers use infrared light to produce precise markings on various materials. Standard fiber lasers operate in the near-infrared spectrum around 1,064 nm (1.06 µm); this range of infrared light tends to react well with metals and plastics. 

But infrared lasers also produce heat and can cause unwanted charring, along with debris and particulates that risk contaminating the surface. This often requires an extra cleaning step, and therefore some manual downtime.

Why are fiber and CO₂ lasers less effective than UV lasers for plastics?

CO2 and fiber lasers have limitations when it comes to marking certain types of plastics. On water bottles and other similar plastics, for example, fiber lasers are often unsuitable because their infrared wavelength can pass through the material, without producing the intended mark.

CO2 lasers at  10.6 um can use their laser induced heat to mark the materials by melting or engraving the surface. This leads to heat-related distortion or deformation, which can be fine for an application such as marking water bottles. But the accuracy and distortion of the CO2 laser mark is not appropriate for high-resolution application marks.

Which Plastics Can Be Laser Marked with UV Lasers

Laser Marking Additives

UV lasers can mark some plastics without additives, providing clean, high-contrast marks on materials that already possess the necessary photochemical properties. Many base plastic materials, however, lack the physical and chemical properties needed to change color. In those cases, laser-sensitive additives is added to the plastic formulation to create the color change and contrast needed for a clear, permanent mark.

Common Additive Materials

The two most commonly used additives are mica and titanium dioxide (TiO2). Mica provides excellent light-scattering properties to enhance visibility. TiO2 offers strong UV absorption and reflection characteristics. Both respond reliably to UV laser energy and create visible contrast on surfaces.

You can also add pigments to the mixture to achieve specific colors. Besides titanium oxide for white or light marks, other colorants may be used, such as antimony-doped tin oxide for gray tints or carbon blacks for dark marks.

Colored plastics typically don’t need additional additives as the plastic already contains pigments that respond to UV lasers. When using near-infrared lasers on clear plastics, custom additives may be required to achieve contrast without compromising transparency. UV lasers, however, can often mark clear substrates directly without additives.

Cost and Application Selection

Additives do increase material costs, so the decision to use them depends on your product’s value and application requirements.

Lower-value products, such as disposable containers or basic consumer goods, often won’t justify the added material costs. Typically, manufacturers use the base plastic properties or select formulations that mark well without additives.

High-value and regulated products, however, may require higher levels of marking. Medical devices, precision automotive components, aerospace parts, and high-end electronics require permanent, high-contrast marks for regulatory compliance, traceability, and safety.

Black laser marking on white plastic

Dark Marking on Light-Colored Plastic

A high-contrast color change occurs when laser marking light-colored plastics. The process can produce various shades of gray depending on the UV laser settings and material. 

White laser marking on black plastic bottle

White Marking on Dark Colored Plastic

Photo bleaching the colorant within the plastic with a UV laser produces various shades of white on a dark substrate.

Transparent Plastic Tube Laser Marking

Transparent Plastic Laser Marking

Transparent plastics are blends of different chemicals, and the UV laser reacts differently with each component. The desired result is usually black or gray marks of varying contrasts.

Types of Laser Marking for Plastics

Color Change (Discoloration)

Plastic laser marking colors

UV lasers can produce markings by changing the color of the plastic: light colors turn dark through photochemical reactions, while dark colors turn white through photo bleaching. 

Foaming

Plastic laser foaming process

When the laser hits the material, gas bubbles (foam) form within the plastic, which causes the surface to rise and appear whitish. This method is typically used on dark materials to get white marks and can be performed with UV, CO2, fiber, or green lasers. Foaming is only suitable when the change in dimension doesn’t matter.

Carbonization

Plastic laser carbonization process

Marking through carbonization involves heating up the material close to its combustion point. This process requires the presence of carbon in the material, since it is the carbon that turns dark.

Engraving

Plastic laser engraving process

Engraving is when the fiber, CO2, or UV laser goes deep into the material (UV lasers are slower to engrave than other lasers, due to low power levels) Engraving produces deep & permanent marks that are more resistant to mechanical abrasion, but it does alter the surface of the material and heat & stress can potentially damage the material.

Ablation

Similar to engraving, ablation removes material, but typically on a micron scale, without heating the surrounding surface.

Safety Considerations for Laser Marking on Plastics

Eyes

Polycarbonate shielding is sufficient for protecting the eyes when using a UV or CO2 laser. Fiber and green lasers, however, require specially coated plastics or glass for eye protection, which are more costly.

Fumes and Particles

Regardless of laser type, fume extraction is always important when marking plastic. In general terms, UV lasers produce the least amount of fumes, fiber lasers produce more, and CO2 lasers produce the most fumes.

Different plastics also release different fumes when exposed to laser energy. Some materials, particularly those containing chlorine or fluorine, can produce corrosive or toxic gases. So, extraction systems must be adequately sized for your materials.

Industries that Benefit from Plastic Laser Marking

The versatility of laser marking on plastics makes it a highly effective solution for a wide range of industries:

Automotive

Laser marking is used in the automotive industry to mark essentially any plastic part for identification and traceability. This includes buttons, headlight lamps, wires, electronic components, and more.
Not only does this technique improve production efficiency, but it also ensures companies are compliant with regulatory standards.

Electronics

UV laser marking is particularly useful in the electronics industry because of its ability to label very small components with highly accurate and clear results: microchips, wires, cables, connectors, plastic encapsulated circuits, and other electronic parts.

Medical

Since manufacturers of medical devices are under strict government regulations to ensure the well-being of all patients, the safety and reliability of laser marking makes it a preferred method for the permanent identification of plastic components.

This applies to catheters, catheter hubs, mouthguards, dental appliances, IV bags, tubes, and more.

Packaging

Every packaging material made of plastic that requires branding, traceability, or identification benefits from laser marking technology: plastic bags, containers, clamshells, etc. 

Consumer Goods

This can be just about anything: cosmetics, water bottles, toys, USB drives, bottle caps… 

FAQs — Frequently Asked Questions About Laser Marking on Plastic

What information can be laser marked on plastic parts?

Laser marking systems offer remarkable versatility in what can be applied to plastic surfaces. Common markings include:

  • Data Matrix codes
  • QR codes
  • Serial numbers
  • Logos
  • Batch numbers
  • UDI codes
  • Date codes
  • Human-readable text
  • Security mark (very small, not consumer-viewable)

How small can laser markings on plastic be?

UV laser systems achieve exceptionally small marking capabilities, with standard spot sizes down to seven microns on all types of plastics. If you need even greater precision, custom systems can produce smaller mark sizes using UV nanosecond, femtosecond, or picosecond lasers.

Is laser marking better than inkjet printing or labels?

Laser marking creates permanent marks that won’t degrade and can’t be removed. In contrast, inkjet printing and labels are not permanent and subject to wear, fading, and damage from moisture. For critical applications, especially medical devices that enter the body, ink and labels are not acceptable.

When it comes to costs, laser marking system have a higher upfront investment, but low ongoing costs over time. Inkjet and label systems will be less expensive at the start but require continuous expenses for ink and label stock. Also, laser marking on plastic eliminates human intervention in the marking process (eliminating the process of unclogging print heads or restocking labels).

Can laser marking be integrated into an automated production line?

Laser marking systems integrate seamlessly into high-speed production lines with on-the-fly marking capabilities. The laser controller requires encoder signals from the conveyor belt to synchronize with production speed, as well as optical trigger signals to identify when a part is positioned for marking. 

How do you choose the right laser marking system for plastic?

Selecting the best laser marking for plastic requires testing. You can send product samples to us to determine the right contrast marking levels and marking speed on the materials you’ll use. Our engineers will evaluate spot size, power level, energy level, repetition rate, and other critical parameters to find the best solution given your specific material, design requirements, and production constraints.

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